DISTINGUISHED MCKNIGHT UNIVERSITY PROFESSOR; FACULTY DIRECTOR, INDUSTRIAL PARTNERSHIP FOR RESEARCH IN INTERFACIAL AND MATERIALS ENGINEERING (IPRIME)
The processing of materials plays a central role in the disciplines of chemical engineering and materials science. Materials often are in a liquid or liquid-like state while being processed, and have interfaces with other media. Many such materials also contain complex structural elements like colloidal particles, polymer chains, and surfactant aggregates whose size is much larger than that of typical solvent molecules.
Our research involves integration of transport phenomena, colloid and interface science, rheology, applied and computational mathematics, and experiments to address fundamental issues motivated by problems in materials processing. These fundamental investigations are frequently inspired by industrial applications in areas such as coating and printing processes, polymer processing, nanofluidics/microfluidics, and energy. Topics of current interest include:
Dynamic wetting: Dynamic wetting is crucial to processes where liquid displaces another fluid along a solid surface, such as the deposition of a liquid coating onto a moving substrate or the displacement of oil in rock pores. Our efforts are aimed at improving fundamental understanding of dynamic wetting, and harnessing that understanding to address materials-processing-related issues such as the transfer of liquid between two separating surfaces and the entrainment of air in high-speed coating processes.
Interfacial instabilities: Instabilities at interfaces are usually undesirable in materials processing operations, but can sometimes be exploited for scientific and technological purposes (e.g., creating a topographically patterned surface). These instabilities can be driven by a variety of sources, including hydrodynamic, electrostatic, and intermolecular forces. We are interested in characterizing when and how interfacial instabilities occur, and in developing ways to control them.
Interfacial flows of suspensions: The successful large-scale manufacture of emerging products in the energy and electronics industries requires that particulate suspensions be coated and printed at high speeds with minimal defects. By combining ideas from colloidal rheology and interfacial fluid mechanics, we are examining a number of model problems in this area.
Polymer dynamics near surfaces: The behavior of polymers near surfaces plays a key role in a variety of applications including biosensors, suspension rheology, and the development of novel nanostructured materials. In many cases, the surface may be patterned chemically and/or topographically, and fluid flows and electric fields may be present. We are applying Brownian dynamics simulations to study how fluid flow, electric fields, and surface patterning can be designed to manipulate the behavior of macromolecules near surfaces. Various molecular theories are leveraged to guide the simulations and to understand the results.
- See CV
- A Thin-film Model for Droplet Spreading on Soft Solid Substrates (with V. Charitatos), Soft Matter 16, 8284-8298 (2020).
- Dynamic Wetting Failure in Shear-thinning and Shear-thickening Liquids (with V. Charitatos, W. J. Suszynski, and M. S. Carvalho), J. Fluid Mech. 892, A1 (27 pages) (2020).
- Cavity Filling with Shear-thinning Liquids (with J.-T. Wu, L. F. Francis, and M. S. Carvalho), Phys. Rev. Fluids 5, 054003 (19 pages) (2020)
- Simultaneous Liquid Flow and Drying on Rotating Cylinders (with C. Parrish), Phys. Rev. Fluids 5, 034001 (27 pages) (2020)
- Effects of Shear and Extensional Rheology on Liquid Transfer between Two Flat Surfaces (with J.-T. Wu and M. S. Carvalho), J. Non-Newtonian Fluid Mech. 274, 104173 (12 pages) (2019).
- Dynamic Wetting Failure in Curtain Coating: Comparison of Model Predictions and Experimental Observations (with C.-Y. Liu and M. S. Carvalho), Chem. Eng. Sci. 195, 74-82 (2019).
- Emptying of Gravure Cavities containing Shear-thinning and Shear-thickening Liquids (with J.-T. Wu and M. S. Carvalho), J. Non-Newtonian Fluid Mech. 268, 46-55 (2019).
- Electrostatic Assist of Liquid Transfer between Plates and Cavities (with C.-H. Huang and M. S. Carvalho), Phys. Rev. Fluids. 4, 044005 (23 pages) (2019).
- Imbibition and Evaporation of Droplets of Colloidal Suspensions on Permeable Substrates (with T. Pham), Phys. Rev. Fluids 4, 034004 (26 pages) (2019).
- Capillary Flow with Evaporation in Open Rectangular Microchannels (with P. Kolliopoulos, K. S. Jochem, R. K. Lade, Jr., and L. F. Francis), Langmuir 35, 8131-8143 (2019).